Take a regular, unencrypted .docx file on your computer, copy it, and rename the extension of the copy from .docx to .zip. If Windows doesn't show the extension at the end of the file name, you'll first need to enable file name extensions from File Explorer.
Now double-click on the renamed file. Your archiver of choice will open it without any problem. Windows itself can open and extract ZIP files without any additional software. Inside, you will see a folder structure containing _rels, docProps, word and a file called [Content_Types].xml at the root.





